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It should work according to my research, though I do recommend trying Linux native alternatives as well. I personally went with Strawberry for now and it is similar enough for me.
I also dual boot on a laptop and a lot of games work well, especially via steam. I do have more problems with my GoG library and I had massive troubles to get Anno installed via Uplay. I’ve also noticed there are a lot of native native Linux ports coming out for some older games as well.
Yes 100% this is the problem. You can even add a redirect to Grub / systemd-boot to load the Windows bootloader from the other drive example for systemd-boot.
Does not work with bitlocker though without diving into very advanced settings to control which events are considered insecure so the tpm releases the keys.